Tensile Behavior of Single-Crystal Tin Whiskers

The growth of metallic (predominantly Sn) whiskers from pure metallic platings has been studied for over 50 years. While the phenomenon of Sn whiskering has been studied for decades, very little is known about the mechanical properties of these materials. This can be attributed to the difficulty in handling, gripping, and testing such fine-diameter and high-aspect-ratio whiskers. We report on the stress–strain behavior of Sn whiskers inside a dual-beam focused ion beam (FIB) with a scanning electron microscope (SEM). Lift-out of the whiskers was conducted in situ in the FIB, and the whiskers were tested using a microelectromechanical system tensile testing stage. Using this technique, the whiskers had minimum exposure to ambient air and were not handled by hand. SEM images after fracture enabled reliable calculation of the whisker cross-sectional area. Tests on two different whiskers revealed relatively high tensile strengths of 720 MPa and 880 MPa, respectively, and a limited strain to failure of ～2% to 3%. For both whiskers, the Young’s modulus was between 42 GPa and 45 GPa. It is interesting to note that the whiskers were quite strong and had limited ductility. These findings are intriguing and provide a basis for further work to understand the effect of Sn whisker mechanical properties on short circuits in electronics.     

Structural,electronic, and optical properties of orthorhombic and triclinic BiNbO4 determined via DFT calculations

We performed ab initio calculations using the FPLAW method with the local density approximation (LDA) implemented in the WIEN2 k code for the orthorhombic (α) and triclinic (β) phases of BiNbO₄. The modified Becke–Johnson exchange potential (mBJ)-LDA approach was also used to improve the electronic properties. The lattice constants calculated for both structures using the LDA are in good agreement with the experimental values. For the band structure calculations, the mBJ-LDA approach provides reasonable agreement for the band gap value compared with the LDA. The estimated (mBJ)-LDA band gap values are 2.89 eV (3.73 eV) and 2.62 eV (3.15 eV) for the α and β phases of BiNbO₄, respectively. Significant optical anisotropy is clearly observed in the visible-light region. We also calculated and evaluated the electron energy loss spectrum for BiNbO₄. This work provides the first quantitative theoretical prediction of optical properties and electron energy loss spectra for both the orthorhombic and triclinic phases of BiNbO₄.     

Study of electroless template synthesized ZnSe nanowires and its characterization

In this work, the successful synthesis of ZnSe nanowires using alumina template by simple and facile electroless template technique has been reported. Morphological characterization of the synthesized nanowires has been done by X-ray diffraction (XRD) and scanning electron microscopy (SEM) measurements. The optical characterizations were conducted by UV–visible and time resolved photo-luminescence. Grain size of synthesized ZnSe nanowires was also calculated using the XRD results. The calculated crystallite size was found to be 6.80 nm. SEM analysis confirms the fabrication of nanowires successfully and it also confirms the size of the nanowires as per the template parameters. The calculated band gap value of 3.03 eV shows the origin of quantum confinement effect in ZnSe nanowires even at the 100 nm scale. The time resolved photoluminescence result indicates that the ZnSe nanowires can be a promising material for luminescent applications in micro-second time domain.     

Effects of annealing on structural and magnetic properties of template synthesized cobalt nanowires useful as data storage and nano devices

Cobalt nanowires of 100 nm diameter were synthesised electrochemically, in the pores of anodic alumina membrane (AAM). Electrochemical impedance spectroscopy was used to study the in situ growth of cobalt nanowires in the AAM. The structural and morphological characterization of template synthesized cobalt nanowires was done through X-ray diffractometer and scanning electron microscope, respectively. Effect of annealing on electrical and magnetic properties of cobalt nanowires was also investigated.     

Disparities in arteriovenous fistula placement in older hemodialysis patients

The benefits of an arteriovenous fistula (AVF) as the preferred vascular access for hemodialysis have been clearly demonstrated. However, only about 20% of patients in the United States initiate hemodialysis with an AVF. In this study, we assessed whether disparities exist in the type of first hemodialysis access placed prior to dialysis start (rather than that used at dialysis initiation), to detect whether certain disadvantaged groups might have lower likelihood of AVF placement. Study cohort of 118,767 incident hemodialysis patients ≥67 years of age (1/2005–12/2008) derived from the United States Renal Data System was linked with Medicare claims data to identify the type of initial access placed predialysis. We used logistic regression model with outcome being the initial predialysis placement of an AVF as opposed to an arteriovenous graft or a central venous catheter. Increasing age, female sex, black race, lower body mass index, urban location, certain comorbidities, and shorter pre–end‐stage renal disease nephrology care are all associated with a significantly lower likelihood of AVF placement as initial access predialysis. Our study suggests the presence of significant disparities in the placement of an AVF as initial hemodialysis vascular access. We suggest that additional attention should be paid to these patient groups to improve disparities by patient education, earlier referral, and close follow‐up.     

DLTS study of annihilation of oxidation induced deep-level defects in Ni/SiO2/n-Si MOS structures

This paper describes the fabrication of MOS capacitor and DLTS study of annihilation of deeplevel defects upon thermal annealing. Ni/SiO₂/n-Si MOS structures fabricated on n-type Si wafers were investigated for process-induced deep-level defects. The deep-level traps in Si substrates induced during the processing of Ni/SiO₂/n-Si have been investigated using deep-level transient spectroscopy (DLTS). A characteristic deep-level defect at E _C = 0·49 eV which was introduced during high-temperature thermal oxidation process was detected. The trap position was found to shift to different energy levels (E _C = 0·43, 0·46 and 0·34 eV) during thermal annealing process. The deep-level trap completely anneals at 350°C. Significant reduction in trap density with an increase in recombination life time and substrate doping concentration as a function of isochronal annealing were observed.     

Quantification of oxidative DNA lesions in tissues of Long-Evans Cinnamon rats by capillary high-performance liquid chromatography-tandem mass spectrometry coupled with stable isotope-dilution method

The purpose of our study was to develop suitable methods to quantify oxidative DNA lesions in the setting of transition metal-related diseases. Transition metal-driven Fenton reactions constitute an important endogenous source of reactive oxygen species (ROS). In genetic diseases with accumulation of transition metal ions, excessive ROS production causes pathophysiological changes, including DNA damage. Wilson's disease is an autosomal recessive disorder with copper toxicosis due to deficiency of ATP7B protein needed for excreting copper into bile. The Long-Evans Cinnamon (LEC) rat bears a deletion in Atp7b gene and serves as an excellent model for hepatic Wilson's disease. We used a sensitive capillary liquid chromatography-electrospray-tandem mass spectrometry (LC-ESI-MS/MS/MS) method in conjunction with the stable isotope-dilution technique to quantify several types of oxidative DNA lesions in the liver and brain of LEC rats. These lesions included 5-formyl-2'-deoxyuridine, 5-hydroxymethyl-2'-deoxyuridine, and the 5'R and 5'S diastereomers of 8,5'-cyclo-2'-deoxyguanosine and 8,5'-cyclo-2'-deoxyadenosine. Moreover, the levels of these DNA lesions in the liver and brain increased with age and correlated with age-dependent regulation of the expression of DNA repair genes in LEC rats. These results provide significant new knowledge for better understanding the implications of oxidative DNA lesions in transition metal-induced diseases, such as Wilson's disease, as well as in aging and aging-related pathological conditions.     

Highly Conductive Carbon Nanotube‐Graphene Hybrid Yarn

An efficient procedure for the fabrication of highly conductive carbon nanotube/graphene hybrid yarns has been developed. To start, arrays of vertically aligned multi‐walled carbon nanotubes (MWNT) are converted into indefinitely long MWNT sheets by drawing. Graphene flakes are then deposited onto the MWNT sheets by electrospinning to form a composite structure that is transformed into yarn filaments by twisting. The process is scalable for yarn fabrication on an industrial scale. Prepared materials are characterized by electron microscopy, electrical, mechanical, and electrochemical measurements. It is found that the electrical conductivity of the composite MWNT‐graphene yarns is over 900 S/cm. This value is 400% and 1250% higher than electrical conductivity of pristine MWNT yarns or graphene paper, respectively. The increase in conductivity is asssociated with the increase of the density of states near the Fermi level by a factor of 100 and a decrease in the hopping distance by an order of magnitude induced by grapene flakes. It is found also that the MWNT‐graphene yarn has a strong electrochemical response with specific capacitance in excess of 111 Fg^?1. This value is 425% higher than the capacitance of pristine MWNT yarn. Such substantial improvements of key properties of the hybrid material can be associated with the synergy of MWNT and graphene layers in the yarn structure. Prepared hybrid yarns can benefit such applications as high‐performance supercapacitors, batteries, high current capable cables, and artificial muscles.